Development of ozone reactivity scales for volatile organic compounds in a Chinese megacity

Development of Ozone Reactivity Scales for Volatile Organic Compounds

Methods for ranking photochemical ozone formation reactivities of volatile organic compounds (VOCs) are discussed. Photochemical mechanisms for the atmospheric reactions of 118 VOCs were used to calculate their effects on ozone formation under various NOx conditions in model scenarios representing 39 different urban areas. Their effects on ozone were used to derive 18 different ozone reactivity...

Development and Application of Improved Methods for Measurement of Ozone Formation Potentials of Volatile Organic Compounds

This project was aimed at developing improved and lower-cost alternative experimental procedures for evaluating chemical mechanisms for predicting ozone impacts of volatile organic compounds (VOCs). More precise measurements of effects of VOCs on OH radicals in chamber experiments could be obtained if 1,3,5-trimethylbenzene is used instead of m-xylene as the radical tracer, but our ability to m...

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity

Toluene and benzene are used for assessing the ability to measure disjunct eddy covariance (DEC) fluxes of Volatile Organic Compounds (VOC) using Proton Transfer Reaction Mass Spectrometry (PTR-MS) on aircraft. Statistically significant correlation between vertical wind speed and mixing ratios suggests that airborne VOC eddy covariance (EC) flux measurements using PTR-MS are feasible. Citymedia...

Mathematical Modeling for Volatile Organic Compounds Removal in a Biofilter: Model Validation and Sensitivity Analysis

synthesis of 3-aryl-2h-benzo[b]-1,4-oxazines in [omim]bf4 and reduction of organic compounds in methylimidazolium formate

در این پروژه ترکیبات 3-آریل-2h-بنزو[b]-4،1-اکسازین ها از مواد اولیه تجاری مشتقات دو آمینو فنول و ?-هالو کتون های آروماتیک در مایع یونی 1-اکتیل-3-متیل ایمیدازولیوم تترا فلورو بورات([omim]bf4) سنتز شده است. این واکنش توسط باز پتاسیم کربنات محلول از طریق o-آلکیلاسیون و سپس یک واکنش آمیداسیون درون مولکولی خود بخود در مدت زمان کوتاه انجام می شود. ترکیبات 4،1-بنزوکسازین به این روش با بهره خوب تا آلی ...